Aluminium (UK: /ˌæljʉˈmɪniəm/ ( listen) AL-yew-MIN-ee-əm)[5] or aluminum (US: /əˈluːmɨnəm/ ( listen) ə-LOO-mi-nəm) is a silvery white member of the boron group The boron group is the series of elements in group 13 in the periodic table. The boron group consists of boron (B), aluminium (Al), gallium (Ga), indium (In), thallium (Tl), and ununtrium (Uut) of chemical elements A chemical element is a pure chemical substance consisting of one type of atom distinguished by its atomic number, which is the number of protons in its nucleus. The term is also used to refer to a pure chemical substance composed of atoms with the same number of protons. Common examples of elements are iron, copper, silver, gold, hydrogen, carbon,. It has the symbol Al and its atomic number In chemistry and physics, the atomic number is the number of protons found in the nucleus of an atom and therefore identical to the charge number of the nucleus. It is conventionally represented by the symbol Z. The atomic number uniquely identifies a chemical element. In an atom of neutral charge, the atomic number is also equal to the number of is 13. It is not soluble in water under normal circumstances. Aluminium is the most abundant metal The abundance of a chemical element measures how relatively common the element is, or how much of the element there is by comparison to all other elements. Abundance may be variously measured by the mass-fraction , or mole-fraction (fraction of atoms, or sometimes fraction of molecules, in gases), or by volume fraction. Measurement by volume- in the Earth Earth is the third planet from the Sun, and the densest and fifth-largest of the eight planets in the Solar System. It is also the largest of the Solar System's four terrestrial planets. It is sometimes referred to as the World, the Blue Planet,[note 6] or by its Latin name, Terra.[note 7]'s crust In geology, a crust is the outermost solid shell of a rocky planet or moon, which is chemically distinct from the underlying mantle. The crusts of Earth, our Moon, Mercury, Venus, Mars, Io, and other planetary bodies have been generated largely by igneous processes, and these crusts are richer in incompatible elements than their respective mantles, and the third most abundant element, after oxygen Oxygen (pronounced /ˈɒksɨdʒɨn/, OK-si-jin, from the Greek roots ὀξύς (acid, literally "sharp", from the taste of acids) and -γενής (-genēs) (producer, literally begetter), is the element with atomic number 8 and represented by the symbol O. It is a member of the chalcogen group on the periodic table, and is a highly and silicon Silicon is the most common metalloid. It is a chemical element, which has the symbol Si and atomic number 14. A tetravalent metalloid, silicon is less reactive than its chemical analog carbon. It makes up about 8% by weight of the Earth's solid surface. Aluminium is too reactive chemically to occur in nature as a free metal. Instead, it is found combined in over 270 different minerals A mineral is a naturally occurring solid chemical substance that is formed through geological processes and that has a characteristic chemical composition, a highly ordered atomic structure, and specific physical properties. By comparison, a rock is an aggregate of minerals and/or mineraloids and does not have a specific chemical composition.[6] The chief source of aluminium is bauxite Bauxite is the most important aluminium ore. This form of rock consists mostly of the minerals gibbsite Al3, boehmite γ-AlO(OH), and diaspore α-AlO(OH), in a mixture with the two iron oxides goethite and hematite, the clay mineral kaolinite, and small amounts of anatase TiO2. Bauxite was named after the village Les Baux in southern France, where ore An ore is a type of rock that contains minerals with important elements including metals. The ores are extracted through mining; these are then refined to extract the valuable element.

Aluminium is remarkable for the metal's low density and for its ability to resist corrosion Corrosion is the disintegration of an engineered material into its constituent atoms due to chemical reactions with its surroundings. In the most common use of the word, this means electrochemical oxidation of metals in reaction with an oxidant such as oxygen. Formation of an oxide of iron due to oxidation of the iron atoms in solid solution is a due to the phenomenon of passivation Passivation is the process of making a material "passive", usually by the deposition of a layer of oxide on its surface. In air, passivation affects the properties of almost all metals in air - notable examples being aluminium, zinc, titanium, and silicon. In the context of corrosion, passivation is the spontaneous formation of a hard. Structural components made from aluminium and its alloys Aluminium alloys are alloys in which aluminium is the predominant metal. Typical alloying elements are copper, zinc, manganese, silicon, and magnesium. There are two principal classifications, namely casting alloys and wrought alloys, both of which are further subdivided into the categories heat-treatable and non-heat-treatable. About 85% of are vital to the aerospace Aerospace comprises the atmosphere of Earth and surrounding space. Typically the term is used to refer to the industry that researches, designs, manufactures, operates, and maintains vehicles moving through air and space. Aerospace is a very diverse field, with a multitude of commercial, industrial and military applications industry and are very important in other areas of transportation Transport or transportation is the movement of people and goods from one location to another. Modes of transport include air, rail, road, water, cable, pipeline, and space. The field can be divided into infrastructure, vehicles, and operations and building. Its reactive nature makes it useful as a catalyst Catalysis is the change in rate of a chemical reaction due to the participation of a substance called a catalyst. Unlike other reagents that participate in the chemical reaction, a catalyst is not consumed by the reaction itself. A catalyst may participate in multiple chemical transformations. Catalysts that speed the reaction are called positive or additive in chemical mixtures, including ammonium nitrate The chemical compound ammonium nitrate, the nitrate of ammonia with the chemical formula N explosives An explosive material, also called an explosive, is a substance that contains a great amount of stored energy that can produce an explosion, a sudden expansion of the material after initiation, usually accompanied by the production of light, heat, sound, and pressure. An explosive charge is a measured quantity of explosive material, to enhance blast power.

Contents

Characteristics

Etched surface from a high purity (99.9998%) aluminium bar, size 55×37 mm

Aluminium is a soft, durable, lightweight, ductile Ductility is a mechanical property that describes the extent in which solid materials can be plastically deformed without fracture and malleable Ductility is a mechanical property that describes the extent in which solid materials can be plastically deformed without fracture metal A metal is a chemical element that is a good conductor of both electricity and heat and forms cations and ionic bonds with non-metals. In chemistry, a metal is an element, compound, or alloy characterized by high electrical conductivity. In a metal, atoms readily lose electrons to form positive ions (cations). Those ions are surrounded by with appearance ranging from silvery to dull gray, depending on the surface roughness. Aluminium is nonmagnetic and nonsparking. It is also insoluble in alcohol, though it can be soluble in water in certain forms. The yield strength The yield strength or yield point of a material is defined in engineering and materials science as the stress at which a material begins to deform plastically. Prior to the yield point the material will deform elastically and will return to its original shape when the applied stress is removed. Once the yield point is passed some fraction of the of pure aluminium is 7–11 MPa The pascal is the SI derived unit of pressure, internal pressure, stress, Young's modulus and tensile strength. It is a measure of force per unit area, defined as one newton per square metre. In everyday life, the pascal is perhaps best known from meteorological barometric pressure reports, where it occurs in the form of hectopascals (1 hPa ≡ 100, while aluminium alloys Aluminium alloys are alloys in which aluminium is the predominant metal. Typical alloying elements are copper, zinc, manganese, silicon, and magnesium. There are two principal classifications, namely casting alloys and wrought alloys, both of which are further subdivided into the categories heat-treatable and non-heat-treatable. About 85% of have yield strengths ranging from 200 MPa to 600 MPa.[7] Aluminium has about one-third the density The density of a material is defined as its mass per unit volume. The symbol of density is ρ . In some countries (for instance, in the United States), density is also defined as its weight per unit volume . The density of a substance is the reciprocal of its specific volume, a representation commonly used in thermodynamics and stiffness An elastic modulus, or modulus of elasticity, is the mathematical description of an object or substance's tendency to be deformed elastically when a force is applied to it. The elastic modulus of an object is defined as the slope of its stress-strain curve in the elastic deformation region: of steel Steel is an alloy that consists mostly of iron and has a carbon content between 0.2% and 2.1% by weight, depending on the grade. Carbon is the most common alloying material for iron, but various other alloying elements are used, such as manganese, chromium, vanadium, and tungsten. Carbon and other elements act as a hardening agent, preventing. It is easily machined Conventional machining, one of the most important material removal methods, is a collection of material-working processes in which power-driven machine tools, such as lathes, milling machines, and drill presses, are used with a sharp cutting tool to mechanically cut the material to achieve the desired geometry. Machining is a part of the, cast In metalworking, casting involves pouring a liquid metal into a mold, which contains a hollow cavity of the desired shape, and then is allowed to solidify. The solidified part is also known as a casting, which is ejected or broken out of the mold to complete the process. Casting is most often used for making complex shapes that would be difficult, drawn Drawing is a metalworking process which uses tensile forces to stretch metal. It is broken up into two types: sheet metal drawing and wire, bar, and tube drawing. The specific definition for sheet metal drawing is that it involves plastic deformation over a curved axis. For wire, bar, and, tube drawing the starting stock is drawn through a die to and extruded Extrusion is a process used to create objects of a fixed cross-sectional profile. A material is pushed or drawn through a die of the desired cross-section. The two main advantages of this process over other manufacturing processes are its ability to create very complex cross-sections and work materials that are brittle, because the material only.

Corrosion Corrosion is the disintegration of an engineered material into its constituent atoms due to chemical reactions with its surroundings. In the most common use of the word, this means electrochemical oxidation of metals in reaction with an oxidant such as oxygen. Formation of an oxide of iron due to oxidation of the iron atoms in solid solution is a resistance can be excellent due to a thin surface layer of aluminium oxide Aluminium oxide is the family of inorganic compounds with the chemical formula Al2O3. It is an amphoteric oxide and is commonly referred to as alumina, corundum as well as many other names, reflecting its widespread occurrence in nature and industry. Its most significant use is in the production of aluminium metal, although it is also used as an that forms when the metal is exposed to air, effectively preventing further oxidation Redox describes all chemical reactions in which atoms have their oxidation number (oxidation state) changed. This can be either a simple redox process, such as the oxidation of carbon to yield carbon dioxide (CO2) or the reduction of carbon by hydrogen to yield methane (CH4), or a complex process such as the oxidation of sugar(C6H12O6) in the. The strongest aluminium alloys are less corrosion resistant due to galvanic A Galvanic cell, named after Luigi Galvani, is an electrochemical cell that derives electrical energy from chemical reactions taking place within the cell. It generally consists of two different metals connected by a salt bridge, or individual half-cells separated by a porous membrane. It is sometimes called a "Voltaic cell", after reactions with alloyed copper Copper is a chemical element with the symbol Cu (Latin: cuprum) and atomic number 29. It is a ductile metal with very high thermal and electrical conductivity. Pure copper is rather soft and malleable, and a freshly exposed surface has a pinkish or peachy color. It is used as a thermal conductor, an electrical conductor, a building material, and a.[7] This corrosion resistance is also often greatly reduced when many aqueous salts are present, particularly in the presence of dissimilar metals.

Aluminium atoms are arranged in a face-centered cubic The cubic crystal system is a crystal system where the unit cell is in the shape of a cube. This is one of the most common and simplest shapes found in crystals and minerals (fcc) structure. Aluminium has a stacking-fault energy The stacking-fault energy is a material property on a very small scale. It is noted as γSFE in units of joules per square meter of approximately 200 mJ/m2.[8]

Aluminium is one of the few metals that retain full silvery reflectance in finely powdered form, making it an important component of silver paints. Aluminium mirror finish has the highest reflectance In photometry and heat transfer, reflectivity is the fraction of incident radiation reflected by a surface. In general it must be treated as a directional property that is a function of the reflected direction, the incident direction, and the incident wavelength. However it is also commonly averaged over the reflected hemisphere to give the of any metal in the 200–400 nm (UV Ultraviolet light is electromagnetic radiation with a wavelength shorter than that of visible light, but longer than x-rays, in the range 10 nm to 400 nm, and energies from 3eV to 124 eV. It is so named because the spectrum consists of electromagnetic waves with frequencies higher than those that humans identify as the colour violet) and the 3,000–10,000 nm (far IR Infrared light is electromagnetic radiation with a wavelength between 0.7 and 300 micrometres, which equates to a frequency range between approximately 1 and 430 THz) regions; in the 400–700 nm visible range it is slightly outperformed by tin Tin is a chemical element with the symbol Sn and atomic number 50. It is a main group metal in group 14 of the periodic table. Tin shows chemical similarity to both neighboring group 14 elements, germanium and lead, like the two possible oxidation states +2 and +4. Tin is the 49th most abundant element and has, with 10 stable isotopes, the largest and silver Silver is a metallic chemical element with the chemical symbol Ag and atomic number 47. A soft, white, lustrous transition metal, it has the highest electrical conductivity of any element and the highest thermal conductivity of any metal. The metal occurs naturally in its pure, free form (native silver), as an alloy with gold and other metals, and and in the 700–3000 (near IR) by silver, gold Gold is a chemical element with the symbol Au (from Latin: aurum, "shining dawn", hence adjective, aureate) and an atomic number of 79. It has been a highly sought-after precious metal for coinage, jewelry, and other arts since the beginning of recorded history. The metal occurs as nuggets or grains in rocks, in veins and in alluvial, and copper.[9]

Aluminium is a good thermal In heat transfer, conduction is the transfer of thermal energy between neighboring molecules in a substance due to a temperature gradient. It always takes place from a region of higher temperature to a region of lower temperature, and acts to equalize temperature differences. Conduction takes place in all forms of matter, viz. solids, liquids, and electrical conductor In physics and electrical engineering, a conductor is a material which contains movable electric charges. In metallic conductors, such as copper or aluminum, the movable charged particles are electrons . Positive charges may also be mobile in the form of atoms in a lattice that are missing electrons (known as holes), or in the form of ions, such, having 62% the conductivity of copper Copper is a chemical element with the symbol Cu (Latin: cuprum) and atomic number 29. It is a ductile metal with very high thermal and electrical conductivity. Pure copper is rather soft and malleable, and a freshly exposed surface has a pinkish or peachy color. It is used as a thermal conductor, an electrical conductor, a building material, and a. Aluminium is capable of being a superconductor Superconductivity is an electrical resistance of exactly zero which occurs in certain materials below a characteristic temperature. It was discovered by Heike Kamerlingh Onnes in 1911. Like ferromagnetism and atomic spectral lines, superconductivity is a quantum mechanical phenomenon. It is also characterized by a phenomenon called the Meissner, with a superconducting critical temperature of 1.2 kelvins The kelvin is a unit increment of temperature and is one of the seven SI base units. The Kelvin scale is a thermodynamic (absolute) temperature scale referenced to absolute zero, the absence of all thermal energy. So by definition, the temperature of a substance at absolute zero is zero kelvin (0 K). The secondary reference point on the Kelvin and a critical magnetic field of about 100 gauss (10 milliteslas).[10]

Creation

Stable aluminium is created when hydrogen fuses with magnesium in either large stars or in supernovae.[11]

Isotopes

Main article: Isotopes of aluminium

Aluminium has nine isotopes, whose mass numbers range from 23 to 30. Only 27Al (stable isotope) and 26Al (radioactive isotope, t1/2 = 7.2×105 y) occur naturally; however, 27Al has a natural abundance above 99.9%. 26Al is produced from argon in the atmosphere by spallation caused by cosmic-ray protons. Aluminium isotopes have found practical application in dating marine sediments, manganese nodules, glacial ice, quartz in rock exposures, and meteorites. The ratio of 26Al to 10Be has been used to study the role of transport, deposition, sediment storage, burial times, and erosion on 105 to 106 year time scales.[12] Cosmogenic 26Al was first applied in studies of the Moon and meteorites. Meteoroid fragments, after departure from their parent bodies, are exposed to intense cosmic-ray bombardment during their travel through space, causing substantial 26Al production. After falling to Earth, atmospheric shielding drastically reduces 26Al production, and its decay can then be used to determine the meteorite's terrestrial age. Meteorite research has also shown that 26Al was relatively abundant at the time of formation of our planetary system. Most meteorite scientists believe that the energy released by the decay of 26Al was responsible for the melting and differentiation of some asteroids after their formation 4.55 billion years ago.[13]

Natural occurrence

See also: Aluminium in Africa

In the Earth's crust, aluminium is the most abundant (8.3% by weight) metallic element and the third most abundant of all elements (after oxygen and silicon).[14] Because of its strong affinity to oxygen, however, it is almost never found in the elemental state; instead it is found in oxides or silicates. Feldspars, the most common group of minerals in the Earth's crust, are aluminosilicates. Native aluminium metal can be found as a minor phase in low oxygen fugacity environments, such as the interiors of certain volcanoes.[15] It also occurs in the minerals beryl, cryolite, garnet, spinel and turquoise.[16] Impurities in Al2O3, such as chromium or cobalt yield the gemstones ruby and sapphire, respectively.[14] Pure Al2O3, known as corundum, is one of the hardest materials known.[16]

Although aluminium is an extremely common and widespread element, the common aluminium minerals are not economic sources of the metal. Almost all metallic aluminium is produced from the ore bauxite (AlOx(OH)3-2x). Bauxite occurs as a weathering product of low iron and silica bedrock in tropical climatic conditions.[17] Large deposits of bauxite occur in Australia, Brazil, Guinea and Jamaica but the primary mining areas for the ore are in Ghana, Indonesia, Jamaica, Russia and Surinam.[18] Smelting of the ore mainly occurs in Australia, Brazil, Canada, Norway, Russia and the United States.[18] Because smelting is an energy-intensive process, regions with excess natural gas supplies (such as the United Arab Emirates) are becoming aluminium refiners.

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