Antimony (pronounced /ˈæntɨmɵnɪ/ AN-ti-mo-nee);[note 2] Latin Latin is an Italic language originally spoken in Latium and Ancient Rome. With the Roman conquest, Latin was spread to countries around the Mediterranean, including a large part of Europe. Romance languages such as Aragonese, Corsican, Catalan, French, Italian, Portuguese, Romanian, Sardinian, Spanish and others, are descended from Latin, while: stibium) is a chemical element A chemical element is a pure chemical substance consisting of one type of atom distinguished by its atomic number, which is the number of protons in its nucleus. The term is also used to refer to a pure chemical substance composed of atoms with the same number of protons. Common examples of elements are iron, copper, silver, gold, hydrogen, carbon, with the symbol Sb and an atomic number In chemistry and physics, the atomic number is the number of protons found in the nucleus of an atom and therefore identical to the charge number of the nucleus. It is conventionally represented by the symbol Z. The atomic number uniquely identifies a chemical element. In an atom of neutral charge, the atomic number is also equal to the number of of 51. It has two stable isotopes, one with seventy neutrons, the other with seventy-two. A silvery lustrous grey metalloid Metalloid, or semi metal, is a term used in chemistry when classifying the chemical elements. On the basis of their general physical and chemical properties, nearly every element in the periodic table can be termed either a metal or a nonmetal. However, a few elements with intermediate properties are referred to as metalloids . The line that, it is found mainly as antimony sulfide, commonly known as stibnite Stibnite, sometimes called antimonite, is a sulfide mineral with the formula Sb2S3. This soft grey material crystallizes in an orthorhombic space group. It is the most important source for the metalloid antimony. The abbreviation for antimony, Sb, is taken from stibnite.

Elemental antimony has applications in electronics Electronics is the branch of science and technology which makes use of the controlled motion of electrons through different media and vacuum. The ability to control electron flow is usually applied to information handling or device control. Electronics is distinct from electrical science and technology, which deals with the generation, and as an alloy with other metals it is used for small arms Small arms is a term of art used by armed forces to denote infantry weapons an individual soldier may carry. The description is usually limited to revolvers, pistols, submachine guns, carbines, assault rifles, rifles, sniper rifles, squad automatic weapons, light machine guns, and sometimes hand grenades. Shotguns, general purpose machine guns, ammunition.

Contents

Etymology

The ancient words for antimony mostly have, as their chief meaning, kohl Kohl is a mixture of soot and other ingredients used predominantly by women in the Middle East, North Africa, the Horn of Africa and South Asia to darken the eyelids and as mascara for the eyelashes. It is also sometimes spelled kol, kehal or kohal in the Arab world, and is known as surma or kajal in South Asia, the sulfide of antimony. Pliny the Elder Gaius Plinius Secundus , better known as Pliny the Elder, was a Roman author, naturalist, and natural philosopher as well as naval and army commander of the early Roman Empire and personal friend of the emperor Vespasian. Spending most of his spare time studying, writing or investigating natural and geographic phenomena in the field, he wrote an, however, distinguishes between male and female forms of antimony; his male form is probably the sulfide, while the female form, which is superior, heavier, and less friable, is probably native metallic antimony.[2]

The Egyptians called antimony mśdmt; in hieroglyphics The characters that are relatively old seem to originate from Sumer or Elam in Mesopotamia[citation needed]. The hieroglyphs that were originally used for recording agricultural products and handicrafts led to the birth of linear and cuneiform script, widely used by the Sumerians, Assyrians and Babylonians. 5000 years ago, Ancient Egyptians had, the vowels are uncertain, but there is an Arabic tradition that the word is ميسديميت mesdemet.[3][4] The Greek word, στίμμι stimmi, is probably a loan word By contrast, a calque or loan translation is a related concept, whereby it is the meaning or idiom that is borrowed rather than the lexical item itself. The word loanword is itself a calque of the German Lehnwort, while calque is a loanword from French from Arabic or Egyptian sdm

, and is used by the Attic tragic Tragedy is a form of art based on human suffering that offers its audience pleasure. While most cultures have developed forms that provoke this paradoxical response, tragedy refers to a specific tradition of drama that has played a unique and important role historically in the self-definition of Western civilization. That tradition has been poets A poet is a person who writes poetry. A poet's work can be literal, meaning that his work is derived from a specific event, or metaphorical, meaning that his work can take on many meanings and forms. Poets have existed since antiquity, in nearly all languages, and have produced works that vary greatly in different cultures and time periods of the 5th century BC; later Greeks also used στἰβι stibi, as did Celsus Aulus Cornelius Celsus was a Roman encyclopedist, known for his extant medical work, De Medicina, which is believed to be the only surviving section of a much larger encyclopedia. The De Medicina is a primary source on diet, pharmacy, surgery and related fields, and it is one of the best sources concerning medical knowledge in the Roman world. The and Pliny Gaius Plinius Secundus , better known as Pliny the Elder, was a Roman author, naturalist, and natural philosopher as well as naval and army commander of the early Roman Empire and personal friend of the emperor Vespasian. Spending most of his spare time studying, writing or investigating natural and geographic phenomena in the field, he wrote an, writing in Latin, in the first century AD. Pliny also gives the names stimi [sic], larbaris, alabaster Alabaster is a name applied to varieties of two distinct minerals: gypsum and calcite (a carbonate of calcium). The former is the alabaster of the present day; generally, the latter is the alabaster of the ancients, and the "very common" platyophthalmos, "wide-eye" (from the effect of the cosmetic). Later Latin authors adapted the word to Latin as stibium. The Arabic word for the substance, as opposed to the cosmetic, can appear as تحميض، ثمود، وثمود، وثمود ithmid, athmoud, othmod, or uthmod. Littré suggests the first form, which is the earliest, derives from stimmida, (one) accusative for stimmi.[5]

The use of Sb as the standard chemical symbol for antimony is due to the 18th century chemical pioneer, Jöns Jakob Berzelius Friherre Jöns Jacob Berzelius was a Swedish chemist. He worked out the modern technique of chemical formula notation, and is together with John Dalton, Antoine Lavoisier, and Robert Boyle considered a father of modern chemistry. He began his career as a physician but his researches in physical chemistry were of lasting significance in the, who used this abbreviation of the name stibium. The medieval Latin form, from which the modern languages and late Byzantine Greek Medieval Greek, also known as Byzantine Greek, is the stage of the Greek language between the beginning of the Middle Ages around 600 A.D. and the Ottoman conquest of the city of Constantinople in 1453. The latter date marked the end of the Middle Ages in Southeast Europe. From the seventh century onwards, Greek was the only language of, take their names, is antimonium. The origin of this is uncertain; all suggestions have some difficulty either of form or interpretation. The popular etymology, from ἀντίμοναχός anti-monachos or French antimoine, still has adherents; this would mean "monk-killer", and is explained by many early alchemists Alchemy, possibly derived from the Arabic word al-kimia , is both a philosophy and an ancient practice focused on the attempt to change base metals into gold, investigating the preparation of the "elixir of longevity", and achieving ultimate wisdom, involving the improvement of the alchemist as well as the making of several substances being monks, and antimony being poisonous.[note 3] So does the hypothetical Greek word ἀντίμόνος antimonos, "against one", explained as "not found as metal", or "not found unalloyed".[6][7] Lippmann conjectured a Greek word, ανθήμόνιον anthemonion, which would mean "floret", and he cites several examples of related Greek words (but not that one) which describe chemical or biological efflorescence In chemistry, efflorescence is the loss of water (or a solvent) of crystallization from a hydrated or solvated salt to the atmosphere on exposure to air.[8]

The early uses of antimonium include the translations, in 1050-1100, by Constantine the African Constantine the African (c. 1020 – 1087) was an eleventh-century translator of Greek and Islamic medical texts of Arabic medical treatises.[9] Several authorities believe that antimonium is a scribal corruption of some Arabic form; Meyerhof derives it from ithmid;[10] other possibilities include Athimar, the Arabic name of the metal, and a hypothetical *as-stimmi, derived from or parallel to the Greek.[11]

History

One of the alchemical symbols Alchemic symbols, originally devised as part of the protoscience of alchemy, were used to denote some elements and some compounds until the 18th century. Note that while notation like this was mostly standardized, style and symbol varied between alchemists, so this page lists the most common for antimony

Antimony's sulfide compound, antimony(III) sulfide, Sb2S3 was recognized in antiquity, at least as early as 3000 BC The city states of Sumer and the kingdom of Egypt are established and grow to prominence. Agriculture spreads widely across Eurasia. World population in the course of the millennium doubles, approximately from 7 to 14 million people.

An artifact made of antimony dating to about 3000 BC was found at Tello Ngirsu is modern Tell Telloh, Dhi Qar Governorate, Iraq, and it was a city of ancient Sumer, situated some 25 kilometres (16 mi) northwest of Lagash. Because of the initial nasal velar ŋ, the transcription of Ĝirsu is usually spelled as Ngirsu (also: G̃irsu, Girsu, Jirsu) to avoid confusion, Chaldea Chaldea or Chaldaea , "the Chaldeans" of the KJV Old Testament, was a marshy land located in Southern Iraq and Kuwait which came to rule Babylon. Tribes of settlers who arrived in the region in 625-539 BC became known as the Chaldeans. Where they originally came from is unknown although Diodorus Siculus states the Egyptians believed the (part of present-day Iraq Iraq , officially the Republic of Iraq (Arabic: جمهورية العراق (help·info) Jumhūrīyat Al-Irāq, Kurdish: كؤماری عێراق‎, Komara Îraqê) is a country in Western Asia spanning most of the northwestern end of the Zagros mountain range, the eastern part of the Syrian Desert and the northern part of the Arabian Desert), and a copper object plated with antimony dating between 2500 BC and 2200 BC has been found in Egypt Egypt (pronounced /ˈiːdʒɪpt/ ; Arabic: مصر‎ Miṣr, pronounced [misˤɾ] ( listen); Arabic: مِصْر Miṣr [ˈmisˤɾ]; Egyptian Arabic: مَصْر Maṣr [ˈmɑsˤɾ]; Coptic: Ⲭⲏⲙⲓ, kīmi; Egyptian: 𓆎𓅓𓏏𓊖 Kemet), officially the Arab Republic of Egypt, is a country mainly in North Africa, with the Sinai Peninsula.[7] There is some uncertainty as to the description of the artifact from Tello. Although it is sometimes reported to be a vase, a recent detailed discussion reports it to be rather a fragment of indeterminate purpose.[12] The first European description of a procedure for isolating antimony is in the book De la pirotechnia of 1540 by Vannoccio Biringuccio, written in Italian. This book precedes the more famous 1556 book in Latin by Agricola Georgius Agricola was a German scholar and scientist. Known as "the father of mineralogy", he was born at Glauchau in Saxony. His real name was Georg Pawer; Agricola is the Latinised version of his name, Pawer/(Bauer) meaning farmer. He is best known for his book De Re Metallica, De re metallica De re metallica (Latin for On the Nature of Metals ) is a book cataloguing the state of the art of mining, refining, and smelting metals, published in 1556. The author was Georg Bauer, whose pen name was the Latinized Georgius Agricola. The book remained the authoritative text on mining for 180 years after its publication, even though Agricola has been often incorrectly credited with the discovery of metallic antimony. A text describing the preparation of metallic antimony that was published in Germany in 1604 purported to date from the early fifteenth century, and if authentic it would predate Biringuccio. The book, written in Latin, was called "Currus Triumphalis Antimonii" (The Triumphal Chariot of Antimony), and its putative author was a certain Benedictine Benedictine refers to the spirituality and consecrated life in accordance with the Rule of St Benedict, written by Benedict of Nursia in the sixth century for the cenobitic communities he founded in central Italy. The most notable of these is Monte Cassino, the first monastery founded by Benedict around 529 monk, writing under the name Basilius Valentinus Basilius Valentinus, also known under the Anglicized version of his name, Basil Valentine, was a 15th-century alchemist. He was the Canon of the Benedictine Priory of Sankt Peter in Erfurt, Germany. Even his name cannot be corroborated; during the 18th century it was suggested that he was Johann Thölde. The year given for his birth in Mainz, 1394,. Already in 1710 Wilhelm Gottlob Freiherr von Leibniz Gottfried Wilhelm Leibniz (German pronunciation: [ˈɡɔtfʁiːt ˈvɪlhɛlm fɔn ˈlaɪpnɪts] (July 1, 1646 - June 21, 1716) was a German mathematician and philosopher. He wrote primarily in Latin and French, after careful inquiry, concluded that the work was spurious, that there was no monk named Basilius Valentinus, and the book's author was its ostensible editor, Johann Thölde (ca. 1565-ca. 1624). There is now agreement among professional historians that the Currus Triumphalis... was written after the middle of the sixteenth century and that Thölde was likely its author.[13][14] An English translation of the "Currus Triumphalis" appeared in English in 1660, under the title The Triumphant Chariot of Antimony. The work remains of great interest, chiefly because it documents how followers of the renegade German physician, Philippus Theophrastus Paracelsus Paracelsus was a Renaissance physician, botanist, alchemist, astrologer, and general occultist. "Paracelsus", meaning "equal to or greater than Celsus", refers to the Roman encyclopedist Aulus Cornelius Celsus from the first century known for his tract on medicine. He is also credited for giving zinc its name, calling it zincum von Hohenheim (of whom Thölde was one), came to associate the practice of alchemy with the preparation of chemical medicines.

According to the traditional history of Middle Eastern alchemy, pure antimony was well known to Jābir ibn Hayyān, sometimes called "the Father of Chemistry", in the 8th century. Here there is still an open controversy: Marcellin Berthelot Marcellin Pierre Eugène Berthelot (25 October 1827 – 18 March 1907) was a French chemist and politician noted for the Thomsen-Berthelot principle of thermochemistry . He synthesized many organic compounds from inorganic substances and disproved the theory of vitalism. He is considered as one of the greatest chemists of all time, who translated a number of Jābir's books, stated that antimony is never mentioned in them, but other authors[who?][15] claim that Berthelot translated only some of the less important books, while the more interesting ones (some of which might describe antimony) are not yet translated, and their content is completely unknown.

The first natural occurrence of pure antimony ('native antimony') in the Earth's crust In geology, a crust is the outermost solid shell of a rocky planet or moon, which is chemically distinct from the underlying mantle. The crusts of Earth, our Moon, Mercury, Venus, Mars, Io, and other planetary bodies have been generated largely by igneous processes, and these crusts are richer in incompatible elements than their respective mantles was described by the Swedish Historically Norse paganism, Christianity and more recently Secularism. Also see Religion in Sweden scientist and local mine district engineer Anton von Swab in 1783. The type-sample In some natural sciences, type locality — or type locale — is the typical or representative location and is typically the first example of a newly discovered or described object. Often it is namesake for the term was collected from the Sala Silvermine in the Bergslagen mining district of Sala, Västmanland Västmanland County is a county or län in central Sweden. It borders to the counties of Södermanland, Örebro, Dalarna and Uppsala. The county also has a stretch of shoreline towards Mälaren (Sweden's third largest lake), Sweden Sweden (pronounced /ˈswiːdən/ SWEE-dən, Swedish: Sverige pronounced [ˈsveːrijə] ( listen)), officially the Kingdom of Sweden (Swedish: Konungariket Sverige (help·info)), is a Nordic country on the Scandinavian Peninsula in Northern Europe. Sweden has land borders with Norway to the west and Finland to the northeast, and water borders with.[16]

Characteristics

Physical properties

A vial containing a black allotrope of antimony Native massive antimony with oxidation Redox reactions describe all chemical reactions in which atoms have their oxidation number (oxidation state) changed. This can be either a simple redox process, such as the oxidation of carbon to yield carbon dioxide (CO2) or the reduction of carbon by hydrogen to yield methane (CH4), or a complex process such as the oxidation of sugar(C6H12O6) in products

There are four known allotropes Allotropy or allotropism is the property of some chemical elements to exist in two or more different forms, known as allotropes of these elements. Allotropes are different structural modifications of an element; the element's atoms are bonded together in a different manner of antimony: a stable metallic form, and three meta-stable forms which are explosive, black and yellow. Each has its own distinct physical properties, the most common of which is metallic antimony, a brittle A material is brittle if it is liable to fracture when subjected to stress. That is, it has little tendency to deform before fracture. This fracture absorbs relatively little energy, even in materials of high strength, and usually makes a snapping sound, silver-white shiny metal. When molten antimony is slowly cooled to metallic antimony, it forms with an hexagonal crystal structure, isomorphic In abstract algebra, an isomorphism is a bijective map f such that both f and its inverse f −1 are homomorphisms, i.e., structure-preserving mappings. In the more general setting of category theory, an isomorphism is a morphism f: X → Y in a category for which there exists an "inverse" f −1: Y → X, with the property that both f with that of the grey form of arsenic Arsenic is the chemical element that has the symbol As, atomic number 33 and atomic mass 74.92. Arsenic was first documented by Albertus Magnus in 1250. Arsenic is a notoriously poisonous metalloid with many allotropic forms, including a yellow (molecular non-metallic) and several black and grey forms (metalloids). Three metalloidal forms of.

The explosive form of antimony is formed from the electrolysis of antimony(III) trichloride, under specific temperatures and concentration. In a bath of hydrochloric with an antimony anode and platinum foil cathode, explosive antimony is deposited on the latter. When scratched with a sharp implement, an exothermic In thermodynamics, the term exothermic describes a process or reaction that releases energy usually in the form of heat, but also in the form of light (e.g. a spark, flame, or explosion), electricity (e.g. a battery), or sound(e.g. burning hydrogen). Its etymology stems from the Greek prefix ex- (meaning "outside") and the Greek word reaction occurs and white fumes given off as metallic antimony is formed; alternatively, when rubbed with a pestle in a mortar, an strong detonation occurs. Black antimony is formed when gaseous metallic antimony is rapidly cooled. It oxidies in air and is sometimes spontaneously combustible. At 100 °C, it gradually transforms into the stable form. Finally, the yellow allotrope of antimony is the most unstable. While it cannot be produced as the black allotrope by rapid cooling, it can only be formed by introducing oxygen into antimony hydride at -90 °C. Above this temperature and in ordinary light, it transforms into the stabler black allotrope.[17]

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